Lead free soldering the primary difference between the solder connections created with processes using tinlead alloys and processes using lead free alloys is related to the visual appearance of the solder. Gold embrittlement in leadfree solder dfr solutions. Ipc 4552a performance specification for electroless nickel immersion gold enig plating for printed boards developedby the platingprocessessubcommittee 414 of the fabricationprocesses committee 410 of ipc usersof this publicationare encouragedto participatein the developmentof futurerevisions. Leadfree solder on gold surface universiti sains malaysia. Gold embrittlement in solder joints circuit design engtips. The general rules for the possible occurrence of liquid metal embrittlement are. An important note contained in the ipc jstd001f 2015 states gold embrittled solder connections can occur regardless of gold thickness when solder volume is low or the soldering process dwell time is not sufficient to allow the gold. Considerable research references 14 has documented the vulnerability of solder joints to gold embrittlement. Gold embrittlement of solder joints in waferlevel chipscale package on printed circuit board with niau surface finish. Qtech gold plated leads and the gold embrittlement issue. Gold embrittlement example of defects soldering flux residue. Qualification of bare boards is performed in accordance to ipc 6012 latest revision qualification and performance specifications for rigid printed boardsand ipc a 610 latest revision acceptability of electronic assemblies, in class 1, 2, and 3, with class 3 designed for the highest reliability for use. In cases where analysis has determined there is a gold embrittlement condition, the gold embrittlement shall be considered a defect, see ipchdbk001 or.
Gold shall be removed from solder terminals plated with 2. If you want to disregard the microscopic level, then what you might come across on a pcb would simply be a poor solder joint with an unknown diagnosis. The present work gives case study examples of various solder joint embrittlement material mechanisms, each with its manufacturing or design solution. Ipc 6010 series qualification and performance specifications ipc a600 acceptability of printed boards printed board assemblies ipc a 610 acceptability of electronic assemblies jstd001 requirements for soldered electrical and electronic assemblies jstd002 033 ipc 77117721 rework, modification and repair of electronic. Figures 5 through 10 show the influence of hydrogen on steel 10. There are several forms of embrittlement in steel like intergranular embrittlement, temper embrittlement, embrittlement caused by overheating and burning. Nsc quality engineering seminar workmanship standards. If an ipc jstd001d requirement is changed or added by this addendum, the clause is listed in jstd001ds table 1 space applications requirements and the entire ipc jstd001d clause is replaced by this addendum except as speci. The need for gold removal on solderable surfaces eptac. Effect of leadfree solder and gold content on the shear strength, toughness, imc and void formation by.
In cases where analysis has determined there is a gold embrittlement condition, the gold embrittlement shall be considered a defect, see ipc hdbk001 or ipc aj820 handbook for guidance. Gold embrittlement can be a significant reliability issue and is a major concern for class 3 highreliability applications. It is recommended that presence and amount of voids are. Although the solder wets the parts, roughness, porosity, and brittleness may be present.
It becomes increasingly more corrosive with increasing temperature and concentration. Liquid metal embrittlement lme is the loss of ductility in normally ductile metals when stressed under contact with liquid metal. The potential for gold embrittlement to occur increases. Iknow that gold will cause leadtin solder joints to become brittle over time. Teresa ferraz and manuela oliveira ciencia e tecnologia dos materiais, vol. However, little is known about the effect of au content on the reliability of snagcu solder joints. Gold embrittlement in solder joints circuit design eng. This is due to gold embrittlement of the solder connection. One of nasas high profile projects is the impending launch of the technologyforward goesr satellite, an engineering breakthrough that will provide significantly more accurate and reliable weather forecasts and severe weather outlooks. Gold embrittlement can be avoided by careful solder joint design and knowledge of. Standard surface mount devices were assembled with. One of nasas high profile projects is the impending launch of the technologyforward goesr satellite, an engineering breakthrough that will provide significantly more accurate and reliable weather forecasts and severe weather. Nevertheless, gold embrittlement related solder joint failures have been analyzed in this laboratory as recently as july 2009.
If these parts are simply soldered to a printed circuit board with leadtin solder, gold embrittlement may ensue. Our ipc certification courses for instructor and operator level like ipca610, ipc. Pretinning of gold plated leads can prevent such embrittlement by dissolving excessive gold, reducing the gold in the resulting solder joint. Ipc aj820 is a supporting document that provides information regarding the intent of this specification content and. This is particularly true where the gold plate is heavy and the amount of solder is small. In certain cases, gold embrittlement may be a threat to the reliability of any glass seal design utilizing tin based solders. Gold embrittlement in solder joints has always been caused by a. Apr 20, 2009 gold au and silver ag embrittlement of solder joints first, the choice of the word embrittlement is unfortunate, because it creates a mental image that is misleading. Gold embrittlement can be avoided by careful solder joint design and knowledge of the causes of this condition. Gold plated leads and the gold embrittlement issue. However, gold generally is regarded as a highly solderable finish. To avoid this issue, prior studies have indicated a maximum gold content of three weight percent. Before soldering to any gold plated surface, you must first remove the gold to conform to ipc 610.
Ipc a 610 has criteria outside the scope of ipc jstd001 defining handling, mechanical and other workmanship requirements. The gold does not diffuse through the solder over time. As originally published in the ipc apex expo conference proceedings. Corrosion by caustic sodium or potassium hydroxide at all concentrations is easily handled at room temperature with a variety of metals and alloys, including carbon steels. There are gold embrittlement test procedures in both ipc tm650 a free download from. Ipca610c, acceptability of electronic assemblies, january 2000. Ipc standards and publications are designed to serve the public interest through eliminating mis understandings. Liquid metal embrittlement and common embrittling couples twi.
Poor joints are often encountered when soldering goldplated parts. The nasa manual has a procedure for removing the gold by diluting it with. F acceptable class 1, 2, 3 for max fillet height clause 8. Gold au and silver agembrittlement of solder joints. Best presented on the recent updates to ipc a 610 and ipc jstd001. Hydrogenembrittlement hydrogeninducedcrackshic hydrogenembrittlementistheprocessbywhichmetalssuchassteelbecomebrittleandfractureduetothein. Liquid metal embrittlement and common embrittling couples. Since steels are particularly prone to hydrogen embrittlement, emphasis is placed on these alloys. You might try papersgoldembrittlementofsolderjoints. Wanhill this report has been prepared as a contribution to the archaeometallurgical literature. Tin whisker mitigation, gold embrittlement solutions. The potential for gold embrittlement to occur increases when the weight of gold is greater than 5% as a ratio of the total solder joint by weight. Gold embrittlement mitigation through lead tinning is the answer to this.
The embrittlement problems and their reliability solutions are discussed over twenty literature references. The contents of this report may be cited on condition that full crcdit is given to nlr aid the author. Aug 27, 2015 the industry rule of thumb is that concentrations below 3 percent gold by weight are acceptable, but this is not a guarantee of risk mitigation as failures have been reported with joints having as low as 1. The standard lead finish on all parts manufactured or supplied by qtech corporation is electrogold plate over electronickel plate per milprf55310. Goldbased alloys offer a variety of advantages that offset the cost of. Standard practice for safeguarding against embrittlement of hotdip galvanized structural steel products and procedure for detecting embrittlement1 this standard is issued under the.
Microstructural embrittlement of gold and silver r. This gold au embrittlement study evaluates tis original fourlayer nickel palladium. As a result, industry standards have been developed to guide cca manufacturers and mitigate the likelihood of circuit failure. Gold embrittlement on a 10 inch wide solder joint if they exist would be the same gold embrittlement that exists in your own solder joint. Solder joint embrittlement mechanisms, solutions and standards. Liquid metal embrittlement lme, also known as liquid metal induced embrittlement, is a phenomenon of practical importance, where certain ductile metals experience drastic loss in tensile ductility or undergo brittle fracture when exposed to specific liquid metals.
Gold contaminated solder joint characterization for. The standard lead finish on all parts manufactured or supplied by qtech corporation is electro gold plate over electronickel plate per milprf55310. This study attempts to provide similar guidance for pbfree sac305 solder. Contractual reference to ipca610 does not additionally impose the content. Porosity versus electrolytic gold thickness from 11. An event is defined as a signal interruption exceeding lasting for greater than 200 nanoseconds.
As an exception to the above, there are specialized soldering finishes, e. The pictures below of the crystalline ausnimc and agsnimc platelets. Low mutual solubility between the liquid and solid metals. Hydrogen embrittlement the action of hydrogen as a result of sulfide corrosion. Supersedes jstd001ds september 2006 joint industry standard. We use an enig finish on all our boards and im wondering if gold embrittlement should be something we should be concerned with regarding short andor long term reliability.
Figures 5 and 7 are a bar that was not cathodically treated, therefore, was. Analyzing the design for acceptability can be a complex process. Absence of intermetallic compound formation between the solidliquid couple. This slide deck was put together by the best staff and present as the differences between f and g webinar series. Gold embrittlement in snpb solder is a wellknown failure mechanism in electronic assembly.
Microscopic study shows the presence of long, hard, white crystals in the solder of such joints. Ipc association connecting electronics industries jedec joint electronic device engineering industry. Most groups of alloys can exhibit failure by cracking in circumstances where the apparent applied stress is well below that at which failure would normally be expected. Cold embrittlement is a condition that occurs when a material is subjected to temperatures that make it less resilient, and therefore more brittle. Jan 31, 2018 best presented on the recent updates to ipc a 610 and ipc jstd001. Effect of gold content on the reliability of snagcu solder joints. The general understanding is that less than 3 wt% of au is acceptable in snpb solder joints. Ipc a 610 acceptability of electronic assemblies jstd001 requirements for soldered electrical and electronic assemblies. It is therefore a potential hazard when handling our liquid products such as nitrogen, oxygen or argon. Gold embrittlement recording rework solderability 9.
Effect on impact strength of 63%tin37% lead solder of increasing concentration of gold figure 2. Lead free soldering the primary difference between the solder connections created with processes using tinlead alloys and processes using lead free alloys is related to. Nsc, quality engineering seminar, workmanship standards, presentation, 2011. Retronix have made a substantial investment in a fully automated retinning and alloy conversion machine to ensure that we provide the best and most reliable service for our partners the system is an ltsqfp system modified to comply with our detailed specifications and provides automated tinning process in accordance with ansi. Generally, a tensile stress, either externally applied or internally present, is needed to induce embrittlement. Gold au and silver ag embrittlement of solder joints first, the choice of the word embrittlement is unfortunate, because it creates a mental image that is misleading. The data suggests how to improve gold plating requirements, for solder joint embrittlement prevention, in solder assembly industry standards.
Investigation of gold embrittlement in connector solder joints. Gold embrittlement eutectic tinlead microstructure with gold embrittlement bse sem image at 3400x. Figure 4 shows a vanadium wire that literally shattered when it was cathodically charged with hydrogen in an electrolytic cell 9. Gold embrittlement in leadfree solder craig hillman, nathan blattau, joelle arnold, thomas johnston, stephanie gulbrandsen dfr solutions, julie silk agilent technologies, alex chiu agilent technologies. Gold removal is performed to reduce the risk of failure associated with embrittled solder. Standard surface mount devices were assembled with snpb and sac305 solder onto printed boards with various thicknesses of gold.
The pictures below of the crystalline ausnimc and agsnimc platelets and their impact on the solder joint structure illustrate the phenomenon much better. This gold au embrittlement study evaluates tis original fourlayer nickelpalladium. Effect of gold content on the reliability of snagcu solder. Embrittlement of solder by gold from plated surfaces. Automatic retinning and alloy conversion of leaded devices. Supersedes jstd001ds september 2006 joint industry. Steels are no exception to this, and probably exhibit a wider variety of failure mechanisms than any other. This chapter outlines the factors which cause hydrogen embrittlement, its subsequent effects and failure mechanisms, and then elaborates on methods for reducing or eliminating the problem. An acceptable method is to tin the surface and then remove the tinning with solder wick. Gold au and silver agembrittlement of solder joints first, the choice of the word embrittlement is unfortunate, because it creates a mental image that is misleading. While cleavage fracture in steels is a common form of embrittlement, in many cases the embrittlement is. Soldering guidelines for land grid array packages peregrine. This is a fact that all package designers should keep in mind.
Solder joint embrittlement mechanisms, solutions and. Ipc aj820a assembly and joining handbook developed by the assembly and joining subcommittee 735 of the product assurance committee 730 of ipc users of this publication are encouraged to participate in the development of future revisions. Standard practice for safeguarding against embrittlement. Gold contaminated solder joint characterization for quantifying risks associated with gold embrittlement. Gold embrittlement of solder joints has been written about for at least four decades 1 3. Deploying cga technology micross components, a global provider of specialty electronic components with a 35 year history in providing authentic, highreliability products, has acquired ibms column grid array line including all equipment, intellectual property, licenses and process flows. A table of solder and gold volumes, which produce 3. Nsc quality engineering seminar workmanship standards jeannette plante nasa workmanship program manager february 14, 2011 112009 1.